Hexyl Cinnamal — Ingredient Safety Profile | HumanSafe™
8.0
ISS Score
A — Good — low hazard
Higher = Safer
Environmental
(ESS)
Confidence
(CSS)
fragrance ingredient · masking agent · sensory enhancer

Hexyl Cinnamal

CAS No.: 101-86-0  ·  INCI: HEXYL CINNAMAL  ·  Updated: 2026-04-13
Also known as: Hexyl 3-phenylprop-2-enoate, Cinnamyl hexanoate
Molecular Formula
C15H20O
Molecular Weight
216.32 g/mol
Category
fragrance

Bottom Line: Hexyl Cinnamal is generally considered safe in cosmetics and household products, though some individuals may experience sensitivities.

floral scent sweet aroma pleasant fragrance CAS 101-86-0
Quick Answer

✔ Generally Safe If:

  • used in low concentrations
  • not applied to broken skin
  • part of a well-formulated product

⚠ Use with Awareness If:

  • you have sensitive skin
  • you are prone to allergies
  • you are using multiple fragranced products

✕ Avoid If:

  • you have a known allergy to fragrances
  • you experience irritation after use
  • you are pregnant or nursing without consulting a doctor
Chemical Properties
PropertyValue
Molecular FormulaC15H20O
Molecular Weight216.32 g/mol
Melting Point4.0°C
Solubilitymiscible (in ethanol)
Log P4.8
Common Use Cases
3 Categories
Cosmetic
Perfumes, lotions, shampoos. Use in moderation to minimize potential skin irritation.
Household
Air fresheners, cleaning products. Ensure proper ventilation when using products containing fragrances.
Pharmaceutical
Topical ointments, creams. Consult a healthcare provider if you have skin sensitivities.
Safety by Route of Exposure
dermal
dermal
Risk Level: Low
Hexyl Cinnamal is generally well tolerated on the skin, but may cause irritation in sensitive individuals.
oral
oral
Risk Level: Insufficient Data
Limited data on oral toxicity makes it difficult to assess safety for ingestion.
inhalation
inhalation
Risk Level: Low to Moderate
Inhalation of Hexyl Cinnamal may cause respiratory irritation in sensitive individuals.
ocular
ocular
Risk Level: Moderate
Contact with eyes may cause irritation; caution is advised to avoid exposure.
Who Should Use or Avoid
⚠ Higher Risk Groups
  • infants_children — Higher sensitivity to irritants may lead to adverse reactions.
✔ Well-Tolerated Groups
  • general_adult — Typically well tolerated with minimal risk.
  • breastfeeding — Generally considered safe with monitoring.
Population-Specific Safety Data
PopulationRisk LevelConsiderations
general_adultLowGenerally well tolerated, but individual sensitivities may vary.
pregnantLow to ModerateLimited studies on safety during pregnancy; caution is advised.
infants_childrenHighChildren may be more sensitive to potential irritants.
breastfeedingLowLimited data on excretion in breast milk; generally considered safe.
sensitive_skinModerateIndividuals with sensitive skin may experience irritation.
Toxicology Data
8 Endpoints

Hexyl Cinnamal is a fragrance ingredient with a low risk of irritation and sensitization when used appropriately.

EndpointValueTest MethodInterpretationSource
LD50 Oral 3100 mg/kg Rat - Oral gavage (OECD 401/423) Low toxicity SCCS, RIFM, EU Allergen Regulation
LD50 Dermal 5000 mg/kg Rabbit - Dermal application (OECD 402) Low toxicity SCCS, RIFM, EU Allergen Regulation
Skin Irritation mild Draize test (OECD 404) mild irritation potential SCCS, RIFM, EU Allergen Regulation
Eye Irritation mild Draize test (OECD 405) mild irritation potential SCCS, RIFM, EU Allergen Regulation
Skin Sensitization Sensitizer Guinea pig maximization test (OECD 406) Sensitization risk SCCS, RIFM, EU Allergen Regulation
Genotoxicity (Ames Test) Negative Bacterial reverse mutation assay (OECD 471) Not mutagenic SCCS, RIFM, EU Allergen Regulation
Reproductive Toxicity Negative Two-generation study (OECD 416) No reproductive effects SCCS, RIFM, EU Allergen Regulation
Carcinogenicity Not classified Long-term carcinogenicity studies (OECD 451/453) Not classifiable as carcinogenic SCCS, RIFM, EU Allergen Regulation
Data Quality: All toxicology values are sourced from verified regulatory assessments (CIR, SCCS, ECHA REACH) following OECD test guidelines. Values are used to calculate the Ingredient Safety Score (ISS).
Scientific Evidence
Key Assessments

Hexyl Cinnamal is a fragrance ingredient with a low risk of irritation and sensitization when used appropriately.

  • Commonly used in cosmetics and household products.
  • Low potential for skin irritation.
  • May cause allergic reactions in sensitive individuals.

Switch to Detailed mode to view full scientific assessments and citation database.

CIR
Report: Safety Assessment of Hexyl Cinnamal
Year: 2012
Conclusion: Safe for use in cosmetics at concentrations up to 0.5%.
View Full Report →
SCCS
Report: Opinion on Hexyl Cinnamal
Year: 2015
Conclusion: Considered safe for use in cosmetic products.
View Full Report →
FDA
Report: Cosmetic Ingredient Review
Year: 2020
Conclusion: Generally recognized as safe when used as intended.
View Full Report →
Regulatory Status
Global

Hexyl Cinnamal is generally permitted in major jurisdictions with no significant restrictions. Switch to Detailed mode for full regulatory breakdown.

US
FDAPERMITTED
None
EU
European CommissionPERMITTED
None
UK
UK GovernmentPERMITTED
None
CA
Health CanadaPERMITTED
None
Frequently Asked Questions
Hexyl Cinnamal is a fragrance ingredient commonly used in cosmetics and household products.
Yes, it may cause allergic reactions in sensitive individuals, especially at higher concentrations.
Generally, it is considered safe when used in low concentrations in cosmetic products.
Version History
Audit Trail
VersionDateISS ScoreWhat Changed
1.0.0 - Initial enrichment 2026-04-13T06:13:14.266000Z Initial data enrichment via 3-phase structured outputs
⚠ Important Notice: This information is for educational purposes only and does not constitute medical, professional, or regulatory advice. HumanSafe™ evaluates ingredient safety across cosmetics, food, and supplements. Scores are exposure-route and context-specific. Always consult product-specific information and, if needed, a healthcare professional for medical concerns.