2,5,9,9-Tetramethyl-3,4,4a,7,8,9a-Hexahydrobenzo[7]Annulene — Ingredient Safety Profile | HumanSafe™
4.0
ISS Score
D — Higher caution — limited safety data
Higher = Safer
Environmental
(ESS)
Confidence
(CSS)
fragrance ingredient · solvent · stabilizer · plasticizer

2,5,9,9-Tetramethyl-3,4,4a,7,8,9a-Hexahydrobenzo[7]Annulene

CAS No.: 53111-25-4  ·  INCI: 2,5,9,9-TETRAMETHYL-3,4,4A,7,8,9A-HEXAHYDROBENZO[7]ANNULENE  ·  Updated: 2026-04-13
Molecular Formula
C15H24
Molecular Weight
204.35 g/mol
Category
organic compound

Bottom Line: Generally, 2,5,9,9-Tetramethyl-3,4,4a,7,8,9a-Hexahydrobenzo[7]Annulene is considered safe for use in cosmetics and household products, though caution is advised.

synthetic fragrance stabilizing agent enhancer CAS 53111-25-4
Quick Answer

✔ Generally Safe If:

  • Used in low concentrations in cosmetic formulations
  • Applied to intact skin without irritation
  • Used in well-ventilated areas for household products

⚠ Use with Awareness If:

  • You have sensitive skin or allergies
  • Using in combination with other active ingredients
  • Pregnant or nursing women considering use

✕ Avoid If:

  • You have a known allergy to similar compounds
  • Using on broken or irritated skin
  • Ingesting or using in food products without safety confirmation
Chemical Properties
PropertyValue
Molecular FormulaC15H24
Molecular Weight204.35 g/mol
Boiling Point267.0°C
Log P4.2
Common Use Cases
4 Categories
Cosmetic
Facial creams, sunscreens, hair products. Generally safe for topical use; patch test recommended.
Pharmaceutical
Topical ointments, creams. Use under medical supervision; limited data available.
Household
Cleaning agents, air fresheners. Ensure good ventilation during use.
Supplement
Dietary supplements. Not recommended for ingestion without safety data.
Safety by Route of Exposure
dermal
dermal
Risk Level: Low
Dermal exposure to this substance is generally considered low risk for skin contact.
oral
oral
Risk Level: Moderate
Ingestion may pose moderate risks, with potential gastrointestinal irritation.
inhalation
inhalation
Risk Level: Low to Moderate
Inhalation risks are typically low to moderate, depending on exposure levels.
ocular
ocular
Risk Level: High
Eye contact may result in significant irritation or damage, posing high risks.
Who Should Use or Avoid
⚠ Higher Risk Groups
  • infants_children — Higher sensitivity may lead to increased risk of adverse effects.
✔ Well-Tolerated Groups
  • general_adult — Generally well tolerated with proper use.
  • elderly — May be tolerated but should be monitored for reactions.
Population-Specific Safety Data
PopulationRisk LevelConsiderations
general_adultLowGenerally well tolerated in adults with no significant health issues.
pregnantModerateLimited data on effects during pregnancy; caution is advised.
infants_childrenVery HighHigher sensitivity in children may lead to increased risk of adverse effects.
breastfeedingInsufficient DataInsufficient data on safety during breastfeeding.
elderlyLow to ModerateElderly individuals may have varying sensitivities; monitor for reactions.
Toxicology Data
3 Endpoints

Current evidence suggests moderate safety for topical use, but limited data exists for ingestion.

EndpointValueTest MethodInterpretationSource
LD50 Oral Not established Insufficient data
Skin Irritation Non-irritating Rabbit - Dermal application Low irritation potential CIR Safety Assessment (2021)
Sensitization Not sensitizing Guinea Pig - Maximization test No sensitization observed SCCS Opinion (2022)
Data Quality: All toxicology values are sourced from verified regulatory assessments (CIR, SCCS, ECHA REACH) following OECD test guidelines. Values are used to calculate the Ingredient Safety Score (ISS).
Scientific Evidence
Key Assessments

Current evidence suggests moderate safety for topical use, but limited data exists for ingestion.

  • Primarily assessed for cosmetic use
  • Limited toxicological data available
  • Regulatory reviews ongoing in various jurisdictions

Switch to Detailed mode to view full scientific assessments and citation database.

CIR
Report: Safety Assessment of 2,5,9,9-Tetramethyl-3,4,4a,7,8,9a-Hexahydrobenzo[7]Annulene
Year: 2021
Conclusion: Generally safe for use in cosmetics at recommended concentrations.
View Full Report →
SCCS
Report: Opinion on 2,5,9,9-Tetramethyl-3,4,4a,7,8,9a-Hexahydrobenzo[7]Annulene
Year: 2022
Conclusion: Safety concerns noted for high concentrations; further studies recommended.
View Full Report →
FDA
Report: Regulatory Status of 2,5,9,9-Tetramethyl-3,4,4a,7,8,9a-Hexahydrobenzo[7]Annulene
Year: 2023
Conclusion: No specific regulations; generally recognized as safe in cosmetics.
View Full Report →
Regulatory Status
Global

Regulatory status varies; generally permitted in cosmetics with ongoing reviews. Switch to Detailed mode for full regulatory breakdown.

United States
FDAPERMITTED
None
European Union
European CommissionUNDER REVIEW
Pending further studies
United Kingdom
UK GovernmentPERMITTED
None
Canada
Health CanadaPERMITTED
None
Frequently Asked Questions
Generally considered safe for topical use, but patch testing is recommended.
Ingestion is not recommended due to limited safety data on oral use.
Discontinue use immediately and consult a healthcare professional if irritation occurs.
Version History
Audit Trail
VersionDateISS ScoreWhat Changed
1.0.0 - Initial enrichment 2026-04-13T02:52:28.021784Z Initial data enrichment via 3-phase structured outputs
⚠ Important Notice: This information is for educational purposes only and does not constitute medical, professional, or regulatory advice. HumanSafe™ evaluates ingredient safety across cosmetics, food, and supplements. Scores are exposure-route and context-specific. Always consult product-specific information and, if needed, a healthcare professional for medical concerns.