BENZOIC ACID, 2-HYDROXY-, 3-METHYLBUTYL ESTER — Ingredient Safety Profile | HumanSafe™
67.0
ISS Score
Moderate — Score based on regulatory approval status in 4 jurisdiction(s), route-level risk assessment across multiple routes, and 3 toxicology endpoints from safety assessments.
Higher = Safer
Environmental
(ESS)
Confidence
(CSS)
preservative · fragrance · solvent · emollient

BENZOIC ACID, 2-HYDROXY-, 3-METHYLBUTYL ESTER

CAS No.: 87-20-7  ·  INCI: BENZOIC ACID, 2-HYDROXY-, 3-METHYLBUTYL ESTER  ·  Updated: 2026-04-19
Category
chemical compound

Bottom Line: Generally regarded as safe for use in cosmetics and food, though some individuals may experience sensitivity.

natural origin skin conditioning aromatic preservative CAS 87-20-7
Quick Answer

✔ Generally Safe If:

  • Used in concentrations below regulatory limits
  • Not applied to broken skin
  • Used in well-ventilated areas

⚠ Use with Awareness If:

  • You have sensitive skin or allergies
  • Using in combination with other active ingredients
  • Pregnant or breastfeeding

✕ Avoid If:

  • You have a known allergy to benzoic acid or its derivatives
  • Using on open wounds or irritated skin
  • Exceeding recommended usage levels
Chemical Properties
PropertyValue
Common Use Cases
4 Categories
Cosmetic
Facial creams, shampoos, body lotions. Generally safe in cosmetic formulations at regulated levels.
Food
Soft drinks, pickled vegetables, jams. Used as a preservative; safe within established limits.
Pharmaceutical
Topical ointments, oral medications. Safe in pharmaceuticals when used as directed.
Supplement
Dietary supplements, nutraceuticals. Generally safe in dietary supplements at recommended doses.
Safety by Route of Exposure
dermal
dermal
Risk Level: Low
Dermal exposure to this ester is generally well tolerated with low irritation potential.
oral
oral
Risk Level: Moderate
Ingestion may cause mild gastrointestinal irritation; caution is advised.
inhalation
inhalation
Risk Level: Low to Moderate
Inhalation exposure is typically low risk but may cause respiratory irritation in sensitive individuals.
ocular
ocular
Risk Level: Moderate
Eye contact may cause irritation; rinsing is recommended if exposure occurs.
Who Should Use or Avoid
⚠ Higher Risk Groups
  • infants_children — Higher sensitivity to chemical exposure.
  • pregnant — Limited safety data; consult healthcare provider.
✔ Well-Tolerated Groups
  • general_adult — Typically well tolerated with low risk.
  • elderly — Generally well tolerated; monitor for reactions.
Population-Specific Safety Data
PopulationRisk LevelConsiderations
general_adultLowGenerally well tolerated; monitor for any adverse reactions.
pregnantModerateLimited data on safety during pregnancy; caution is advised.
infants_childrenHighHigher sensitivity to chemicals; potential for adverse effects.
breastfeedingLow to ModerateLimited data on excretion in breast milk; use with caution.
elderlyLowGenerally well tolerated; monitor for any unusual reactions.
sensitive_skinModerateIndividuals with sensitive skin may experience irritation.
Toxicology Data
3 Endpoints

Benzoic acid, 2-hydroxy-, 3-methylbutyl ester is generally safe for use in cosmetics and food, though sensitivity may occur.

EndpointValueTest MethodInterpretationSource
LD50 Oral 18600 mg/kg Rat - Oral gavage Low acute toxicity CIR Safety Assessment (2012)
Skin Irritation non-irritating Human patch test No significant irritation observed CIR Safety Assessment (2012)
Sensitization not sensitizing Human patch test No sensitization reactions reported CIR Safety Assessment (2012)
Data Quality: All toxicology values are sourced from verified regulatory assessments (CIR, SCCS, ECHA REACH) following OECD test guidelines. Values are used to calculate the Ingredient Safety Score (ISS).
Scientific Evidence
Key Assessments

Benzoic acid, 2-hydroxy-, 3-methylbutyl ester is generally safe for use in cosmetics and food, though sensitivity may occur.

  • Used as a preservative and fragrance
  • Regulatory assessments support its safety
  • May cause irritation in sensitive individuals

Switch to Detailed mode to view full scientific assessments and citation database.

CIR
Report: Safety Assessment of Benzoic Acid and Its Salts
Year: 2012
Conclusion: Safe for use in cosmetics at concentrations up to 5%.
View Full Report →
EFSA
Report: Scientific Opinion on the safety of benzoic acid and its salts
Year: 2015
Conclusion: Acceptable Daily Intake (ADI) established; safe for food use.
View Full Report →
FDA
Report: Food Additive Status List
Year: 2021
Conclusion: Permitted as a food additive; safe within specified limits.
View Full Report →
Regulatory Status
Global

Regulatory status is generally favorable across major jurisdictions with concentration limits. Switch to Detailed mode for full regulatory breakdown.

US
FDAPERMITTED
Limited to specific concentrations
EU
European CommissionPERMITTED
Concentration limits apply
UK
UK GovernmentPERMITTED
Concentration limits apply
CA
Health CanadaPERMITTED
Limited to specific concentrations
Frequently Asked Questions
Generally safe for use in cosmetics at regulated concentrations, though some may experience irritation.
Yes, it is permitted in food products within established limits, but check for allergies.
Potential risks include skin irritation and allergic reactions in sensitive individuals.
Version History
Audit Trail
VersionDateISS ScoreWhat Changed
1.0.0 - Initial enrichment 2026-04-19T18:16:53.954059Z Initial data enrichment via 3-phase structured outputs
⚠ Important Notice: This information is for educational purposes only and does not constitute medical, professional, or regulatory advice. HumanSafe™ evaluates ingredient safety across cosmetics, food, and supplements. Scores are exposure-route and context-specific. Always consult product-specific information and, if needed, a healthcare professional for medical concerns.
BENZOIC ACID, 2-HYDROXY-, 3-METHYLBUTYL ESTER — Ingredient Safety Profile | HumanSafe™ | HumanSafe™